PR5211
Individual assignment (MS)
Individual assignment (submission 20/09/2024)
Examine the spectra of both compound 1 and 2. Write a short report (no more than 4 pages/2 sheets) to explain the respective spectrum, focusing on the fragmentation pattern and the identifiable fragments.
Do
• Use schematics and images were possible
• Show rearrangements and mechanism if possible, not only the fragments
• Explain if it is a common reaction (like loss of hydroxy or methyl group)
Don’t
• Fragments without charges or radical
Compound 1
m/z starting with M-H+
315, 287, 271, 257, 232, 230, 100, 98, 84, 81, 56
Compound 2
m/z starting with M-H+
481, 453, 396, 298, 243, 156, 98
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